光助Fenton氧化、化学絮凝法联合处理R盐废水的研究

采用光助Fenton氧化、化学絮凝法联合处理生物难降解的R盐废水,考察了不同反应条件对处理效果的影响.试验结果表明,光助Fenton氧化、化学絮凝法联合处理废水,两者之间存在协同作用,可以提高处理效果,降低处理成本.在最佳试验条件下,R盐废水经光助Fenton氧化、化学絮凝法联合处理后,COD去除率可达90%以上.     

超声-过氧化氢-氧化铜组合技术催化氧化水中苯酚

研究了超声-H2O2-CuO组合技术对苯酚的降解效果。考察了苯酚初始浓度、溶液温度及鼓入空气对苯酚去除率的影响。实验结果表明，与未鼓入空气时相比，连续鼓气时苯酚的降解效果较好；初始浓度低，苯酚去除率高；溶液温度从20％上升到55％时，苯酚去除率随温度升高而增大，温度对该过程的影响主要表现为对催化剂的影响而不是对超声作用的影响。高效液相色谱分析表明，苯酚降解的中间产物主要为对苯二酚、邻苯二酚及其他有机小分子物质，最终产物为草酸、二氧化碳和水。     

Genotoxicity of two novel pesticides for the earthworm, Eisenia fetida

In this paper, several studies were conducted to evaluate the genotoxicity of two pesticides, Imidacloprid and RH-5849, for earthworm (Eisenia fetida). Earthworms were exposed in different exposure systems to evaluate their acute toxicity and the genotoxicity of the two pesticides was evaluated by using the method of sperm deformity assessment, micronucleus test of root tip cells in Vicia faba, a mouse bone-marrow micronucleus test, and comet assay. LC(50) (interpolated concentration at which 50% mortality of test population occurs) for earthworms varied in different exposure systems. The results indicated that Imidacloprid was consistently more toxic than RH-5849 in all exposure systems. In this study, sperm deformity test was used to detect the potential adverse influences of pesticides on the reproduction of earthworms. The results demonstrated that significant induction of sperm deformity (p<0.01) and a dose-effect relationship displayed at Imidacloprid concentrations higher than 0.5 mg/kg dry soil. However, the sperm deformity frequency of groups exposed to RH-5849 did not show significant difference (p>0.05) from the control until the dose reached 100 mg/kg dry soil. The results of the V. faba micronucleus tests showed that micronuclei frequency of the exposed group did not show significant difference (p>0.05) from the control until the concentration of Imidacloprid and RH-5849 reached 100 mg/ml. The results of the mouse bone-marrow micronuclei test also indicate that two pesticides did not show significant effects (p>0.05) on the micronuclei frequency in mice bone-marrow cells until the dose reached 100 mg/kg for Imidacloprid and 300 mg/kg for RH-5849 (2/3 LD(50)). Although no genotoxicity was detected by using the micronucleus tests, the results of the comet assay showed that the two pesticides induce significant DNA damage (p<0.01) in earthworms and dose-effect relationships were displayed. The 'earthworm comet assay' is a rapid and sensitive way to screen chemicals or terrestrial environments for their DNA-damaging properties.     

村镇建设中农村污水处理设施的选择

有机废弃物是村镇环境的主要污染源,污水处理已成为村镇建设中亟待解决的问题。受经济发展水平限制,常规的污水处理设施在村镇难以实施,为此必须采用适合村镇经济水平和管理水平的污水处理方式。针对村镇的实施条件,在对几类小型简易污水处理设施特点进行分析的基础上,提出在村镇建设中易推行结构简单、费用低廉、便于管理、实施方便的沼气发酵池和地埋式无动力污水处理设施,以初步解决村镇污水问题。     

污水处理设施建设与运营模式浅析

详细介绍了国外污水处理设施建设与运营的管理经验,分析了英国、美国、法国和荷兰等典型管理模式的特点,阐述了中国污水处理事业的发展历程,调研了目前国内并存的事业体制、企业化管理、委托运营、DBO（设计-建设-运营）、特许经营、股权转让、合资合作、完全私有化、用户和社区资助等模式并逐一进行分析,指出了中国污水处理设施建设与运营的发展方向,认为应尽量慎重考虑涉及产权的特许经营模式,着力推广DBO模式。     

民主：环境保护的政治基础

通过对全球100多个国家的环境指数比较研究发现,环境保护与民主水平之间的相关性存在统计学的显著性。民主水平无一例外地和5个不同环境评价指标之间的相关性具有明显的统计学显著性。这表明,民主水平的提高有助于促进环境治理、环境可持续发展,有利于降低人们对环境的破坏。为此,解决环境问题需要进行相应的政治体制改革,为环境可持续发展扫除政治方面的障碍。     

金属矿山采选项目的环境管理制度执行情况及问题分析

介绍了金属矿山项目的一般环境影响及特殊环境影响,通过识别金属矿山的特殊环境影响,以金属矿山尾矿库溃坝事故为例,对金属矿山项目环境管理制度执行情况及在管理过程中存在的问题进行了分析。尽管在矿山开采建设及服务过程都伴随着环境制度的监管,但是在实际运行过程中仍会出现不同的问题,产生环境污染影响与生态影响。因此,识别出金属矿山项目采选易发生的环境问题,在开发矿产资源的同时做好矿山环境保护及管理工作、加强矿山环境制度建设及环境监管是非常必要的。     

哈尔滨市水资源基本情况及开发利用现状

以水资源可持续利用支撑经济社会可持续发展为核心,坚持全面规划,统筹兼顾,综合治理原则,紧密结合哈尔滨市水资源具体特点,通过对水资源开发利用现状调查与评价,对经济社会发展过程中中远期各阶段进行需水预测,对水环境治理、城市供水、城市排水和污水处理等方面进行规划,提出哈尔滨市水资源可持续开发利用与保护的对策,强调了水资源的节...     

Removal of 17β-estradiol in laccase catalyzed treatment processes

The removal of 17β-estradiol （E2） in laccase catalyzed oxidative coupling processes was systematically studied in this work. We focused on the influence of pH and natural organic matter （NOM） on the performance of the enzymatic treatment processes. It was found that the optimal pH for E2 removal was between 4 and 6. The removal of E2 was slightly inhibited in the presence of NOM. Enzymatic transformation of E2 was second-order in kinetics with first-order to both the concentrations of the enzyme and contaminant. Mass spectrum （MS） analysis suggested that coupling products were formed through radical-radical coupling mechanism. The results of this study demonstrated that laccase catalyzed oxidative coupling process could potentially serve as a treatment strategy to control steroid estrogens.